胡国政,丁詠雪,魏振澄.ICP发射光谱法测定矿样中痕量稀土元素分量[J].地质找矿论丛,1986,(1):88-93 |
ICP发射光谱法测定矿样中痕量稀土元素分量 |
THE DETERMINATION OF TRACE REE IN GEOLOGICAL SAMPLES BY ICP EMISSION SPECTROMETRY |
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DOI:10.6053/j.issn.1001-1412.1986.1. 009 |
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中文摘要: |
ICP发射光谱法测定矿样中痕量稀土分量本文讨论了以ICP-AES法测定矿样中痕量稀土元素分量方法.实验曾借鉴岩矿测试所的方法5.此方法是将试样经阳离子交换富集,浓缩至小体积,加入内标后,通过气动雾化器将溶液输送到ICP激发,摄取光谱.不同稀土元素的检出限分别为0.00X~0.Xμg/g各被测元素光谱测定相对标准偏差为1.8~4.1%.经GSD-1~GSD-8标样三次分析,以及经半年多来五批样品的生产实践证明,本方法流程简单,分析速度快,易于推广,检出限和精确度基本上能满足需要. |
英文摘要: |
The determinatioon of trace REE by ICP-AES method is discussed in this paper. The REE in samples were preconcentrated through ion-exchange process, and introduced to the ICP using a pneumatic nebulizer. An axially-viewed (end-on) plasmatorch was also selected. The detection limit and analytical accuracy can meet the demands of trace REE analysis. |
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